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The monograph is intended for elucidation of the novel trend in chemical physics regarding the polymer non-crystalline phase. It stresses the physical phenomena affecting the kinetics and mechanism of chemical reactions proceeding in the non-crystalline polymer matrix (NCPM). NCPM is depicted in terms of a supramolecular (carcass-micellar) model. The model is thought to reflect heterophase packing of polymeric chains, which co-operate as a molecular-chain sponge.The NCPM model presented is proved for adequate description of principal structure-physical phenomena to elaborate the scheme of structural-kinetic modeling of chemical reactions in bulky polymers. Structure-physical phenomena elucidated in the monograph are:- peculiarities of polymer plasticization and polymer blending with liquids;- structural and thermodynamic aspects of sorption of low molecular species;- properties of ESR (spin) probes and optical (molecular) probes;- features of water absorbed by polymers;- mechanical and
